| 5,859 | 98 | 146 |
| 下载次数 | 被引频次 | 阅读次数 |
X射线衍射分析(XRD)作为结构研究的一种重要技术手段,在无机合成和其他行业的研究中具有重要的应用。从基本概念和基本原理出发,对XRD的基本理论进行简单的介绍,然后对X射线粉末衍射在无机合成中物相分析的应用研究进展进行综述,以便于更多的研究人员了解和掌握并合理应用XRD。
Abstract：X- ray diffraction(XRD) analysis as an important method for structural research plays an important role in the field of inorganic synthesis chemistry.The basic concepts and principles of XRD is briefly introduced,ignoring the complex computing and derivation of the formula.The recent progresses on the application of X- ray powder diffraction in phase analysis of inorganic synthesis are then discussed in detail.This paper will deliver some important information to scientists who work in this field.
[1]梁敬魁.粉末衍射法测定晶体结构(二)[M].北京:科学出版社,2003.
[2]Matthea A P,Marjorie A L.Comparison of Nanoscaled and Bulk NiO Structural and Environmental Characteristics by XRD,XAFS,and XPS[J].Chem Mater,2012,24:4483~4490.
[3]杨于兴,漆王睿.X射线衍射分析[M].上海:上海交通大学出版社,1989.
[4]胡林彦,张庆军,沈毅.X射线衍射分析的实验方法及其应用[J].河北理工学院学报,2004,26(3):83~86.
[5]刘粤恵,刘平安.X射线衍射分析原理与应用[M].北京:化学工业出版社,2003.
[6]李树棠.晶体X射线衍射学基础[M].北京:冶金工业出版社,1990.
[7]熊文杰,邝先飞,康念铅.X射线在晶体衍射分析中的应用[J].江西化工,2008,(3):137~140.
[8]陈乐生,乔秀清,吴兴合,等.AgCd和AgSn合金粉的相结构分析[J].电工材料,2012,(3):11~13.
[9]蒋晓光,王岭,储刚,等.X射线衍射法(XRD)分析煅烧白云石的物相组成[J].中国无机分析化学,2012,2(1):31~33,36.
[10]Li Z,Wang Y,Liu J,et al.Photocatalytic hydrogen production from aqueous methanol solutions under visible light over Na(Bi x Ta1-x)O3solid solution[J].International Journal of Hydrogen Energy,2009,34(1):147~152.
[11]Zhu D,Zhu H,Zhang Y.Microstructure and magnetization of single-crystal perovskite manganites nanowires prepared by hydrothermal method[J].Journal of Crystal Growth,2003,249(1-2):172~175.
[12]杨伟,陈胜洲,邹汉波,等.氮掺杂碳载钴催化剂制备及其TG-TIR和XRD光谱分析[J].光谱学与光谱分析,2012,32(4):1114~1117.
[13]杨水金.X射线衍射分析在无机合成中的应用[J].赣南师范学院学报,1997,(6):54~56.
[14]杨亚辉,陈启元,李洁,等.硼族元素掺杂对K2La2Ti3O10光催化产氢性能的影响[J].无机化学学报,2009,25(2):256~263.
[15]Soon K K,Sang M J,Sang D K.Quantitative X-ray Diffraction Analysis for Sulfation of Limestonein Flue Gas Desulfurization[J].Ind Eng Chem Res,2000,39:2496~2504.
[16]Mehtap O,Frederic H,Peter S.In Situ Observation of Bimetallic Alloy Nanoparticle Formation and Growth Using High-Temperature XRD[J].Chem Mater,2011,23:2159~2165.
[17]徐玉林,黄永葵,杨水金.H3PW12O40/SiO2催化合成环己酮乙二醇缩酮[J].精细化工,2013,30(6):614~617,655.
[18]Remigijus J,Darius A,Putinas K,et al.XRD,SEM and photoelectrochemical characterization of ZnSe electrodepositedon Cu and Cu-Sn substrates[J].Electrochimica Acta,2012,70:118~123.
[19]Akitoshi H,Kousuke N,Atsushi S,et al.superionic glass-ceramic electrolytes for room-temperature rechargeable sodium batteries[J].Nature Communications,2012,(3):856~860.
[20]Wang J,Hu J,Guo Y,et al.Wurtzite Cu2ZnSnSe4nanocrystals for high-performance organic-inorganic hybrid photodetectors[J].NPG Asia Materials,2012,(4):1~6.
[21]Sanches E A,Soares J C,Mafud A C,et al.Structural characterization of Chloride Salt of conducting polyaniline obtainedby XRD,SAXD,SAXS and SEM[J].Journal of Molecular Structure,2013,1036:121~126.
[22]李明,言智,宓一鸣,等.硅系相变材料的研究进展[J].上海工程技术大学学报,2012,26(3):263~266.
[23]马红,吴凡,郑婷婷.水热法制备Ba5Nb4O15纳米粉体[J].西安邮电学院学报,2012,17(5):89~91,107.
[24]Eddy C E,Laby T H.Quantitative Analysis of Alloys by X-ray Spectroscopy[J].J Phys Chem,1931,35(12):3635~3638.
[25]Zwell L,Danko A W.Applications of X-ray Diffraction Methods to Quantitative Chemical Analysis[J].Applied Spectroscopy Reviews,1975,9(1):168~212.
[26]王晓叶,郑斌,冯志海.X射线衍射全谱拟合定量分析方法研究[J].宇航材料工艺,2012(2):108~110.
[27]Kenji S,Mari M.X-ray Diffraction Imaging of Anatase and Rutile[J].Anal Chem,2010,82:3519~3522.
[28]王治几,张宝莲.洗衣粉中4A沸石X射线定量分析[J].日用化学工业,1992,(5):33~36.
[29]Chung F H.Quantitative interpretation of X-ray diffraction patterns of mixtures.I.Matrix-flushing method for quantitative multicomponent analysis[J].J Appl Cryst,1974,(7):519~525.
[30]李华,孙伟,刘加平.XRD-Rietveld法用于水泥基材料物相的定量分析[J].混凝土,2013,(1):1~5.
基本信息:
DOI：
中图分类号:O657.2;O611.4
引用信息:
[1]徐玉林,徐明波,杨水金.XRD在无机合成中物相分析的应用[J].湖北师范学院学报(自然科学版),2013,33(04):40-46+62.
基金信息:
湖北省教育厅教学研究项目(2012358);; 湖北省教育科学“十二五”规划重点课题(2011A017,2012A024)资助